Sadiq, who won London's mayoral elections in May previous year after defeating multi-billionaire Tory candidate Zac Goldsmith, arrived in Pakistan on Wednesday for a three-day official visit.
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Khan was taken from the border to the city of Lahore in a heavily armed police convoy, which included an ambulance and fire engine, He, however, defied the advice of the Foreign Office officials.
Having visited India earlier, Sadiq Khan is now in Pakistan on a goodwill visit to promote his "London is Open" campaign.
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Several high officials including Karachi Mayor Waseem Akhtar, Sindh Education Minster Jam Mehtab Dahar received the honorable guest at Karachi airport.
Later, Sadiq Khan will call on Sindh Chief Minister Syed Murad Ali Shah and later, he will attend a luncheon to be hosted in his honor at Governor House. Pakistan cricket captain Sarfraz Ahmed will also play in the exhibition match. He arrived in Lahore on Wednesday with his 16-member delegation through the Wagah border with India.
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Karachi is Khan's last stop in Pakistan.